Tuesday, June 19, 2018

Mine Law (Important Laws)

List of Important dates and RA in Mine Law

Spanish Royal Decree - May 14, 1867
US Act of Congress - July 1, 1902
Commonwealth Act No. 137 - The Mining Act

===================================================
RA 7942 - The Philippine Mining Act of 1995

IRRs
  • 96-40
  • 99-57
  • 2000-61
  • 2000-99
  • 2003-46
  • 2004-54
  • 2005-07 (Establishment of the FMRDP)
  • 2005-15
  • 2007-15
  • 2007-26
  • 2010-13 (Ancestral lands and DMT)
  • 2010-21
RA 7076 - People's Small Scale Mining Act
IRR 2015-03 

Marcos Regime
PD 87 - Oil Exploration and Development Act
PD 463 - "Mineral Resources Development Decree of 1974"
PD 972 - Coal Service Contract
PD 1586 - Environmental Impact Statement
Batas Pambansa Blg. 265 - Prohibiting the Extraction of Gravel and Sand from Beaches

Republic Acts
RA 387 - Petroleum Act of 1949
RA 4209 - Geology Profession Law of the Philippines
RA 6969 - Toxic Waste
RA 7586 - NIPAS Act (National Integrated Protected Areas System Act of 1992)
RA 8371 - IPRA (Indigenous People's Right Act of 1997)
RA 8749 - Clean Air Act
RA 9003 - Ecological Solid Waste Management Act
RA 9275 - Clean Water Act
RA 10166 - Geology Profession Regulatory Act of 2012

Executive Orders
EO 79 (2012) No-Go Zones
EO 279 (1987, Cory Aquino) FTAA

Sunday, June 17, 2018

Silica Family Tree (COLLECTED)

Click for bigger view.




Varieties of Some Minerals (COLLECTED)


VARIETIES of MINERALS
            
            BERYL
Ø  GOSHENITE (COLORLESS) – PURE BERYL
Ø  AQUAMARINE (BLUE)       – Fe2+
Ø   EMERALD (GREEN)           – Cr
Ø  HELIODOR (YELLOW)        – Fe3+
Ø  MORGANITE (PINK)          – Mn2+
Ø  BIXBITE (RED)                    – Mn3+

QUARTZ
Ø  ROCK CRYSTAL (CLEAR)                 – PURE Quartz
Ø  AMETHYST (PURPLE)                    – Fe
Ø  ROSE QUARTZ (PINK)                    – Pink Dumortierite
Ø  CITRINE (YELLOW)                        – Fe3+
Ø  MILKY QUARTZ (MILKY WHITE)    – abundant minute fluid inclusions
Ø  SMOKY QUARTZ (BROWN-BLACK) – IRRADIATION OF Qz w/ TRACE AMTS OF Al
Ø  VERMARINE/ AVENTURINE (GREEN)

SILICA
Ø  MOGANITE            – variety of silica found in microcrystalline quartz
Ø  CHALCEDONY        – fibrous microcrystalline quartz and moganite
Ø  CARNELIAN           – reddish-orange chalcedony
Ø  AGATE                   – multi-colored banded chalcedony
Ø  ONYX                     – agate where the bands are straight, parallel and consistent in size

CHERT
Ø  JASPER (RED)         – Fe3+
Ø  FLINT (BLACK)       – Organic Matter

CORUNDUM
Ø  RUBY (RED)           - Cr
Ø  SAPPHIRE (BLUE)  - Fe and Ti

OLIVINE (forsterite)
Ø  PERIDOT (OLIVE GREEN)   - Fe

CHRYSOBERYL
Ø  ALEXANDRITE (Displays COLOR Change which depend on lighting)
Ø  CYMOPHANE (YELLOW)    - Fe3+

GYPSUM
Ø  SELENITE – crystalline, transparent, colorless
Ø  ALABASTER – Massive Gypsum, transluscent

Isomorphs (COLLECTED)

ISOMORPHS


(ORTHORHOMBIC)
FAYALITE         -           Fe2SiO4
FORSTERITE    -           Mg2SiO4

(ISOMETRIC)
GOLD               -           Au
SILVER             -           Ag

(ISOMETRIC)
PERICLASE       -           MgO
GALENA          -           PbS

(MONOCLINIC)
MUSCOVITE
BIOTITE

(ISOMETRIC)
HALITE            -           NaCl
SYLVITE           -           KCl

(HEXAGONAL)
CALCITE           -           CacO3
RHODOCROSITE          MnCO3

Polymorphs (COLLECTED)


POLYMORPHS

(C)
DIAMOND       -           ISOMETRIC
GRAPHITE       -           HEXAGONAL

(CaCO3)
CALCITE           -           HEXAGONAL
ARAGONITE    -           ORTHORHOMBIC

(FeS2)
PYRITE             -           ISOMETRIC
MARCASITE     -           ORTHORHOMBIC

DICKITE           -           MONOCLINIC
KAOLINITE       -           TRICLINIC
           
(Ag2S)
ACANTHITE     -           MONOCLINIC
ARGENTITE     -           ISOMETRIC

(Al2SiO5)
ANDALUSITE
SILLIMANITE
KYANITE


(Cu3 As S4)
ENARGITE       -           ORTHORHOMBIC
LUZONITE        -           TETRAGONAL

(TiO2)
RUTILE             -           TETRAGONAL
ANATASE        -           TETRAGONAL
BROOKITE       -           ORTHORHOMBIC

(SiO2)
QUARTZ          -           HEXAGONAL
TRIDYMITE      -           ORTHORHOMBIC
COESITE          -           MONOCLINIC
STISHOVITE     -           TETRAGONAL
CRISTOBALITE -           TETRAGONAL

(PbS)
WURTZITE       -           HEXAGONAL
SPHALERITE    -           ISOMETRIC


MRP Reviewer (COLLECTED)



METALLICS

IRON
·        A lustrous, ductile, malleable, silver-gray metal.
·        4th most common element in the earth’s crust.
·        2nd most abundant metallic element.

PRINCIPAL IRON MINERALS: Hematite( Varieties: Red Ochre – Red Earthy luster, Specularite- Metallic luster) Magnetite ( Lodestone), Limonite, Goethite, Siderite.

Philippine iron deposits are classified into:
A) SKARN
Limestone or calcareous sediments are intruded by a younger intermediate to acidic pluton
MOST IMPORTANT IRON DEPOSITS IN THE PHILIPPINES


B) MAGNETITE SAND
Deposit type consists of magnetite concentrations in beach and alluvial sand.

 Batas Pambansa Blg. 265 – “ An Act Prohibiting the Extraction of Gravel and Sand from Beaches and Providing Penalties Thereof” which was approved on Nov. 13, 1982. 
C) LATERITE
The deposits are of two types: nickeliferous and aluminous.
  1. ultramafic rocks (e.g., dunite and peridotite) are nickeliferous as these rocks contain significant amounts of nickel that develop into silicate nickel ore (garnierite)
  2. mafic rocks (e.g., gabbro and basalt) are high in alumina (Al2O3) bauxite or bauxitic clay forms.
d) sedimentary
Sedimentary iron deposits are in the form of layers of hematite and/or magnetite interbedded with sediments.
e) bog
Occur in small low-grade deposits with much manganese, phosphorus, water, clay, and other impurities.
f) spring
Originated as spring emanations in Quaternary volcanic terranes.

LOCATION
OPERATOR
HOST ROCK
AGE
SKARN
a. Larap Iron-Copper-Molybdenum  skarn deposit
Larap, Jose Panganiban,
Camarines Norte

The oldest rock suite and host to iron-base metal mineralization consists of the metamorphosed interbedded  marls,  calcareous shales, arkoses,  graywackes, sandstones and conglomerates of the Early Miocene age Universal Formation or Tumbaga Formation intruded by swarms of granodioritic to monzonitic dikes related to a diorite (Tamisan Diorite)stock sw of the ore body.
Late Miocene age

b. Sta.Ines iron-skarn deposit
Santa Ines,
Antipolo, Rizal
Santa Ines Iron and Steel Corporation
Santa Ines Diorite intruded limestone and clastic rocks
Late Eocece to Middle Miocene
c. Lamin iron-skarn deposit

Lammin, Carasi,
Ilocos Norte
Ilocandia Iron and Smelting Incorporated
Diorite and quartz diorite stocks

Oligocene age

MAGNETITE SAND
Sta. Cruz  and Agoo magnetite sand deposits
Sta. Cruz to Tagudin, Ilocos Sur and Agoo,
La Union

The beach sand is fine to medium-grained. Magnetite occurs either as grains disseminated with other alluvial minerals in the sand or within distinct layers that are subcentimeter to 2 cm thick. These coastal areas are underlain by clastic sedimentary rocks of Upper Miocene – Pleistocene age. Magnetite comes from the erosion of older rock units in the Central Cordillera.

Primary mineral: Titanomagnetite
Younger than Upper Miocene –
Pleistocene age.
LATERITE IRON DEPOSITS
Laterite iron deposits of the Surigao Mineral Reservations
The reservation comprises the central eastern portion of Surigao peninsula (Parcel I) in northeastern Mindanao; southern Dinagat, Nonoc, Hinatuan and Masepelid islands and lesser isles (Parcel II); northern Dinagat island (Parcel III); and Siargao and Bucas Grande islands (Parcel IV)

The laterite iron deposits are residual products of chemical weathering of serpentinized ultramafic rocks.
Limonite is the chief constituent of the laterite iron ore while hematite and magnetite occurs in subordinate amounts.  
Pleistocene
SEDIMENTARY BEDDED IRON DEPOSIT
Camalaniugan Sedimentary bedded iron deposit
Geographical name: Bgy. .Camalaniugan, Aparri, Cagayan (10 km south of Aparri Poblacion, Cagayan)  
Central geographic coordinates: 18°18’N, 121°37’E 


The deposit formed within a structural basin that probably ponded into a lake. Iron supplied into this basin originated from the chemical weathering of surrounding rocks, which shows evidence of pyritization probably brought about by dioritic intrusions.

Principal Ore: Hematite and Limonite

SEDIMENTARY BOG IRON DEPOSIT
Taan sedimentary bog iron deposit  
Geographical description: The deposit lies at the southern sector of Nueva Vizcaya near the provincial boundary of Quezon and Nueva Ecija. It is within the interior highland of the Sierra Madre mountains.  
Central geographic coordinates: 15°38’N, 121°19’E  


The upper section of the Pliocene Ilagan Sandstone hosts the iron deposit. Overlying this unit in probable unconformity is a flat-lying, poorly consolidated conglomerate, probably equivalent to the Pleistocene Alat Conglomerate


Principal Ore: Hematite and Magnetite



Nickel
·        A silvery white, magnetic metallic element used chiefly in making alloys.
·        A common by-product of nickel laterite deposits is cobalt.
·        22nd in natural abundance among elements in crustal rock.
Pricnipal Ore: Garnierite, Millerite, Niccolite, Pentlandite, Pyrrhotite
CLASSIFICATION OFDEPOSIT
NICKEL LATERITE

derived from the weathering of underlying ultramafic rocks found along the ophiolite belts of the country form the bulk of nickel deposits.
Localities: Surigao, Palawan and Samar
NICKEL SULFIDES
Magmatic Nickel Sulfide Deposit


Hydrothermal Nickel Sulfide deposit



Magmatic nickel sulfide is closely associated with chromitites and platinum group elements (PGE).
Localities: Acoje, Sta. Cruz, Zambales

occurs in narrow silicified zones in serpentinite rock and in rocks immediately adjacent to it. Known deposits are believed to be epithermal (i.e., formed at shallow depths).

Localities: Leyte and Ilocos Norte

Nickel laterite

LOCATION
OPERATOR
HOST ROCK
AGE
Rio Tub nickel laterite deposit
Barangay Rio Tuba,
Bataraza, Palawan
Rio Tuba  Nickel Corporation
(RTNMC)
Ultramafic Member  of thePalawan Ophiolite, consisting of the Mt.  Beaufort ultramafics and the Espina Formation

The in-situ weathering of the Mt. Beaufort ultramafics resulted in the concentration and enrichment of nickel and cobalt in the preserved laterite (soil) profile.
Late Cretaceous
Hinatuan Island
nickel laterite
deposit
Geographical name: Tagaba-an, Nonoc Island, Surigao del Norte 
Hinatuan Mining
Corporation

ultramafic rock consists predominantly of harzburgite

Nonoc Island
nickel laterite
deposit
Nonoc
Island, Surigao
del Norte
Philnico Mining and
Industrial Corporation
Nickeliferous laterites are developed on the ultramafic rocks.

Limonite Type

Adlay-Cadianao-
Tandawa (ACT)
Project
Carrascal,
Surigao del Sur

QNI Ltd.
The nickel laterites are developed on the ultramafic rocks bordering the eastern portions of Surigao del Norte

The main nickel ore is limonite and garnierite

MAGMATIC NICKEL
Acoje magmatic nickel sulfide deposit
Sitio Pasicar, Sta. Cruz, Zambales
Acoje Mining Corp.

The nickel sulfide lenses are hosted primarily by the black dunite facies.

Nickel sulfide mineralization is dominated by pentlandite although some occurrence of heazlewoodite and godlevskite were also noted.

EPITHERMAL NICKEL
Jaro deposit
Minulho, Jaro Leyte

Nickel sulfides occur along silicified shear zones in the serpentinite as individual grains and as colloform bands

The mineralization is being linked with Pliocene-Pleistocene volcanism.
Pliocene-Pleistocene
volcanism

Limonite zone. The limonite zone, as the term implies, is composed predominantly of iron clay minerals. It is usually capped by reddish-brown soil with low nickel content.  Most often, this capping, termed as overburden in mining parlance, is low in nickel but rich in iron as manifested by the presence of iron pisolites or hard caps. As this material progresses downward, the color usually turns into various shades of yellow and brown (Zone 2, the accumulation zone). It is still rich in iron but the nickel values are now relatively higher than the upper portion. The limonite zone exhibits plasticity and highly porous. Slightly weathered boulders of the bedrock most often appear in the lower portion of the limonite zone.

Saprolite zone. The contact between the limonite and the saprolite (Zone 4) may be gradational or sharp. Depending on the intensity of weathering and laterite development, the saprolite may have variable thickness even in one confined area. This thickness range from less than a meter to more than 8 meters. The saprolite is colored with various shades of green mixed with hues of yellow and brown. It turns into various shades of blue, gray to black as it approaches the bedrock. The iron content becomes sharply and significantly less than in the limonite zone while the magnesium content progressively becomes richer at depth. The higher ore grade is believed to be due to the downward migration of nickel which eventually settles along the numerous cracks in the saprolite. The ubiquitous green coatings along fractures are often due to garnierite, a high grade

Chromium
  • 21st in natural abundance among the elements in crustal rocks.
CLASSIFICATION OF PRIMARY PODIFORM (Orthomagmatic) CHROMITE DEPOSIT
chrome to iron ratio (Cr:Fe)
metallurgical (2.4-3.2:1)
refractory (1.8-2.3:1)
PRIMARY PODIFORM (Orthomagmatic) CHROMITE DEPOSITS
The chromite deposits generally occur within the ultramafic portions of ophiolite complexes. Peridotite rocks that host the mineralization are harzburgite, dunite, and cumulate ultramafic-mafic layers
OPHIOLITE BELTS (Alpine- Type)
1) Zambales Ophiolite
2) Casiguran Ophiolite
3) Angat Ophiolite
4) Eastern Bicol-Eastern Mindanao Ophiolite
5) Western Bicol-Eastern Leyte Ophiolite
6) Central Mindanao Ophiolite
7) Antique Ophiolite
8) Zamboanga-Sulu Ophiolite
9) Palawan Ophiolite.

A complete ophiolite consists of a continuous sequence from top to bottom of metamorphic peridotite, cumulate peridotite, pyroxenite, dunite, chert, spilite, and conformable pelagic sediments that are collectively thought to represent oceanic crust and upper mantle material.
RESIDUAL AND TRANSPORTED CHROMITE DEPOSITS
The chromite deposits in laterite and alluvial/beach placer sands are associated with ultramafic exposures.

LOCATION
OPERATOR
GEOLOGY
AGE



Acoje orthomagmatic
podiform chromite
deposit

Pascal, Sta.
Cruz,
Zambales;

Acoje Mining Corp.

Metallurgical chromite mineralization at Acoje generally occurs as pods, and lenses within the dunite horizon and the basal cumulate mafic sequence.


Coto orthomagmatic
podiform chromite
deposit
Baloganan, Masinloc,
Zambales
Consolidated
Mines, Inc. and operated by Benguet
Corporation
The deposit occurs within the Coto Block
of the Zambales Ophiolite Complex.


Krominco orthomagmatic
stratiform deposits
Dinagat Is.,
Surigao del Norte
Krominco, Incorporated
The chromitite bodies appear as pseudobedded deposits associated with the dunite unit of the Dinagat ophiolite


Samar lateritic (residual)  chromite deposit

Llorente, Hernani and McArthur, Samar
Co-owned by Pacific Shore Mining and Rio
Chico Mining corporations
Chromite occurs mainly as (i) residual concentrations in laterites, (ii) sand as transported alluvial lateritic material deposited in flat areas near the shore and in karsted limestone areas, and (iii) primary chromite as densely disseminated bands and massive lenses in serpenti-nized bedrock.


Batang-Batang alluvial chromite and chromite sand deposit
Narra, Palawan,

Philcrome
Mining
Corporation
Quaternary beach sediments adjacent to the exposed ultramfaic complex of the Palawan Ophiolite



MANGANESE
  • a silver-gray, brittle metallic element used principally in making alloys
  • 12th in abundance among elements in the earth's crust.
ORE: Rhodocrosite, Franklinite, Psilomelane/ Romanechite, Hausmannite, Braunite, Rhodonite, Alabandite, Manganite

Ukraine
is the world’s leading producer of high-grade manganese ore, followed by Georgia, South
Africa, Brazil, and Gabon.

Most of the manganese deposits of commercial importance are confined in a belt
between 45º north latitude and 25º south latitude.
CLASSIFICATION
Primary ( Volcanic-sedimentary) Manganese Deposits
Primary manganese deposits of volcanic-sedimentary origin are those deposits associated with : a) submarine volcanic rocks and chert ; b) tuff and tuffaceous sedimentary rocks and some chert ; and c) chert only.


Secondary (Residual) Manganese Deposits
These deposits are formed by the weathering and reconcentration of manganese from primary bedded manganese oxides.

LOCATION
OPERATOR
GEOLOGY 
AGE
Primary sedimentary and epigenetic deposits and secondary(residual)
Anda Peninsula , Bohol

New Frontier Mines, Inc.
Manganese ore mineralization at the Anda Peninsula offers a low grade residual deposits that consist of fined-grained manganese oxide particles that range in size from 0.2 to 5 centimeters in size containing an average of 20 percent manganese.

Sedimentary

Madulag, Baler, Aurora

Central Mining Corporation.

  The manganese deposits appear to consist of tabular to lenticular through        pockety bodies ranging from a few centimeters to about 3.5 meters thick.

Primary sedimentary deposit

Coron , Busuanga Island, Palawan

Jordan Mining and Industrial Corporation

Manganese occurs as intertonguing layers and/or bedded with chert and jasper.

Residual type

Barangay Camangue Lolloken, Municipality of                 Enrique Villanueva, Siquijor Island, Negros Oriental

Badillo Mining
Corporation

This residual concentration of manganese ore consists  of 1 – 2 meters thick                    sandstones impregnated with manganese oxide of the Basac Formation. The ore                    occurs on the surface as beds, stringers, scattered pebbles and boulders.

Sedimentary and residual deposit

Bawang,Jiabong , Western Samar


The sedimentary deposit consists of tabular to lenticular body in tuffaceous limestone and chert of Cretaceous formation.



Copper
  • a brownish-red metallic element,
  • 25th most abundant element in crustal rocks.
Principal Ore: Chalcopyrite and Bornite, Chalcocite, Covellite, Malachite,Azurite and Chrysocolla.

In the Philippines, the principal sources of copper are porphyry copper deposits associated with dioritic to quartz dioritic and granodioritic stocks and batholiths occurring in major arcs of the Philippines.
Porphyry Copper
  • dioritic to quartz dioritic and granodioritic stocks and batholiths
They are distributed over a wide age range:
Cretaceous in Cebu, Oligocene in Nueva Vizcaya and southeastern Negros, Late Miocene to Pliocene in the Luzon Central Cordillera.
Epithermal/mesothermal vein-type
  • Late Miocene to Pliocene.
VMS
     Kuroko-Type- These are strata-bound polymetallic mineral deposits genetically related to submarine acid volcanic activity
     Cyprus- Type- The Cyprus-type refers to the massive sulfide base metal sulfide ores associated with rocks of mafic-ultramafic association of ophiolitic affinity
     Besshi- Type- The description for the Besshi- or Kieslager-type copper deposits is that of stratabound massive cupriferous iron sulfide deposits, bed-like or lenticular in form, that lie conformably in crystalline schists (Kanehira and Tatsumi, 1970). It is now recognized, however, that these types of deposits are simply metamorphosed VMS deposits, of either the Kuroko or Cyprus types
Vein- Type Copper
     volcanic-hosted Cu-As-Sb veins – HS veins
     mafic/ultramafic-hosted chalcopyrite-pyrrhotitepyrite-quartz veins

Copper Skarn- Skarns are rocks consisting of Ca-Fe-Mg-Mn silicates formed by the replacement of carbonate-bearing rocks accompanied by regional or contact metamorphism and metasomatism, in response to the emplacement of intrusives of varying compositions.
PORPHYRY COPPER

LOCATION
OPERATOR
HOST ROCK
AGE
Sto. Tomas II

Padcal, Tuba, Benguet
Philex Mining Corporation

hornblende quartz
diorite porphyry,

Far Southeast

Mankayan, Beguet
Lepanto Consolidated
Mining
Quartz diorite
porphyry stock

Dinkidi

Didipio, Kasibu, Nueva
Vizcaya
Climax Mining Corporation
dark Diorite

Middle Miocene.

San Antonio

Sta.Cruz, Marinduque

Marcopper Mining
Corporation
granodioritic to quartz dioritic

Carmen

Brgys.
Toledo and
Biga, Toledo
City, Cebu
Atlas Consolidated
Mining and Development
Corporation
Lutopandiorite and intruded rocks.


Kingking

Lawaan,PantuKan,
Compostela Valley

(NADECOR)

diorite intrusive complex
partly by the intruded
metamorphosed volcanics
Miocene diorite intrusives.

Batong-buhay
Pasil, Kalinga

diorite body

Boyungan


Silangan Mindanao
Mining Corporation


VMS DEPOSITS

LOCATION
OPERATOR
HOST ROCK
AGE
Ungay-Malobago- Besshi Type
Pacolbon,Rapu-Rapu,
Albay Prov
Rapu-Rapu Minerals Inc.
altered dacitic volcanic layers that are closely associated with intercalated quartzo-feldspathic (felsic)
schists.
Middle to Late Cretaceous.

Hixbar- Besshi
Karog-kog, Rapu-Rapu, Albay Province
Hixbar Gold Mining Co. /Nielsen and Company
same
same
Canatuan

Sitio Canatuan, Bgy. Tabayo, Siocon,
Zamboanga del Norte
TVI Resource
Development
(Philippines), Inc.
Tungauan schists


Bagacay
Hinabangan, Samar



Sulat
Lonoy and Bonot, Sulat, Eastern Samar
Trident Mining and
Industrial Corp.
dacitic rocks


HIGH SULFIDATION EPITHERMAL
Tampakan

Tampakan, South
Cotabato
Sagittarius Mines
Incorporated

Mineralization in the area is hosted by a sequence of intermediate to alkali volcanics and subvolcanics, which are intruded by rocks of wide range compositions.  Mineralization style is that of an two earlier porphyry copper events telescoped by a highsulfidation epithermal Cu-Au deposit. The two porphyry Cu phases are hosted, respectively younging age, to quartz diorite  and hornblende-biotite diorite.

SKARN
Bessemer

Larap, Jose Panganiban, Camarines Norte


Ore mineralization is largely confined within the skarn zone. Higher grade bodies are in the form of beds roughly parallel to the skarn-shale (hornfels) contact at the footwall



GOLD
  • beauty and resistance to corrosion, most ductile and malleable
  • 75th in order of abundance among the elemen
  • Green gold used in jewelry contains copper and silver; white gold contains zinc and nickel, or platinum metals.
  • Chlorauric acid is used in photography for tonin silver images.
  • Potassium gold cyanide is used in electrogilding.
  • The naturally occurring gold-silver alloy is called electrum. Gold also occurs in telluride (tellurium-bearing) minerals such as calaverite and sylvanite along with silver, and in the mineral nagyagite along with lead, antimony, and sulfur. It occurs with mercury as gold amalgam. It may be occasionally present in the sulfide minerals pyrite, galena and sphalerite. Seawater also contains gold of up to 9 billion metric tons, but its recovery is yet to be economically feasible


SILVER
  • This white, lustrous metallic element conducts heat and electricity better than any other metal.
  • It is next to gold in terms of malleability and ductility.
  • It is harder than gold but softer than copper.
  • 66th among elements in terms of natural abundance in the earth’s crust.
  • Colloidal silver, dilute solutions of silver nitrate (AgNO3), and some insoluble compounds, such as potassium, are used in medicine as antiseptics and bactericides.
  • Argyrol, a silver-protein compound, is a local antiseptic for the eyes, ears, nose, and throat.
  • cerargyrite (or horn silver), pyrargyrite, sylvanite, and argentite.
GEOLOGY AND OCCURENCES
  • tensional splays oblique to the Philippine fault zone
  • Two major magmatic arcs, the Western Luzon and Eastern Philippine arcs, are the most prolific gold producers in the country.
The gold districts are
(1) Baguio-Mankayan gold district along the
western flank of Luzon Central Cordillera;
(2) Camarines Norte Gold District of southeastern Luzon; and
(3) Masbate Gold district in northwestern Masbate Island.
(4) The gold province is the Eastern Mindanao Gold Province consisting of three gold districts, namely, Surigao Gold District, Central Gold District, and Masara Gold District.


Philippine gold deposits may be genetically divided into two groups:
1.       primary-hypogene gold-silver deposits
2.       secondary-supergene deposits




NON METALLICS

Industrial minerals and manufacturing materials including cement raw materials, ceramics and refractory raw materials are dealt with in this chapter.  These minerals and materials are as follows:  






ASBESTOS
-Asbestos though considered a significant industrial mineral utilized in fireproofing, insulation, brake linings and asbestos cement early in 1980’s is now considered non-commercial due to its carcinogenic property.

CLASSIFICATION :
§  Shingles
§  Paper
§  plaster
LOCALITIES

Bangui and Burgos, Ilocos Norte; Aguilar and Mangatarem, Pangasinan; Botolan, Cabangan, San Felipe and San Marcelino, Zambales; Abra de Ilog, Mindoro Occidental; Antique; Misamis Oriental and Bukidnon

§  refuse grade
§  Asbestos
§  Feldspar
§  Talc
§  Barite 
§  Gypsum
§  Cement raw materials
§  Bentonite
§  Limestone
§  Ceramic raw material
§  Clay 
§  Magnesite
§  Refractory raw materials
§  Diatomite
§  Perlite
§  Zeolite
§  Dolomite
Silica  




BARITE

Barite is an inert, heavy and stable mineral; hence, it is also called heavy spar. Oftentimes, it is white, opaque and twinned, though impurities render the mineral different colors like buff, gray and reddish. Barite is produced and sold in several forms: jig concentrate, crude lumps, ground barite, or flotation concentrate.   

LOCALITIES

Mabilog na Bundok, Lobo, Batangas and in Mansalay, Oriental Mindoro
                                                                                                                                                                                                                                    

BENTONITE

  Bentonite is clay consisting predominantly of minerals of the smectite group.

Bentonite is an important mineral commodity used in foundry molding sands, drilling mud, bentonite slurries for sealing porous strata and stoppage of water movement in foundations for buildings, tunnels and dams, iron ore pelletizing, bleaching oils and fats, carriers for insecticides and pesticides, and as component of paints, pharmaceuticals, medicines and cosmetics. 


Commercial bentonite deposits are formed by alteration of fine-grained volcanic debris deposited over relatively large areas. Other bentonite deposits are formed by insitu hydrothermal alteration of coarse-grained intrusive rocks.



CLASSIFICATION:

1.     SWELLING TYPE
They expand considerably, from 15 to 20 times of the original volume of dry material in water and contain sodium as predominant exchangeable ion.
2.     Non Swelling Tyoe
This type has negligible swelling and carries calcium as its principal exchangeable ion.

***Bentonites in the Philippines are generally of the nonswelling type, the bulk of which is classified as fuller’s earth.
LOCALITIES

Pangasinan, Cagayan, Nueva Ecija, Batangas, Quezon , Albay, Cebu, Leyte, Davao del Norte,



GYPSUM

Gypsum is a hydrous calcium sulphate (CaSO4.2H2O) containing 20 percent water. It is obtained either from naturally occurring gypsum-bearing ores or from fertilizer manufacturing, as by-products.  At present, the expanded production capacity of most cement plants in the country requires large volume of gypsum as cement retarder. Likewise, the manufacturing industry has greater need for gypsum in the fabrication of fireproof gypsum board now proliferating among high-rise malls and condominiums.

 LOCALITIES:
     Over the country, the known gypsum deposits are disposed in four (4) provinces: Batangas, Albay, Camarines Sur and Negros Oriental.

LIMESTONE
      Carbonate rocks are extremely common and make up approximately 15% of the sedimentary column. They occur extensively in the Philippine archipelago and vary in age from Cretaceous to Recent.

The cement industry is the largest consumer of limestone.


CLAY

    Clay is an earthy substance consisting chiefly of hydrous aluminum silicates with colloidal material and specks of rock fragments, which generally become plastic when wet and stone-like when fired.

The biggest reserves of siliceous clay in the islands were formed by the residual alteration of chloritic schists in Siruma, Camarines Sur.

CLASSIFICATION:

1.     RESIDUAL
These deposits are widely distributed in the country. Many of these clay deposits are formed from the chemical weathering of feldspar-rich rocks.

           Cagayan, Ilocos Norte, Abra, Benguet, Nueva Ecija, Pangasinan, Zambalez, Bulacan, Rizal, Laguna, Batangas, Quezon, Camarines Norte, Camarines Sur, Sorsogon, Albay, Marinduque, Romblon, Negros Occidental, Iloilo, Panay, Antique, Surigao del Sur, Misamis Oriental, Bukidnon and Zamboanga del Sur and in Zamboanga City.

2.     TRANSPORTED
Transported clays are formed by accumulation in sites such as swamps and basins of clayey materials transported by water





DIATOMITE

    Diatomite or “diatomaceous earth“ consists mainly of siliceous shells or skeletons of single-celled organisms called diatoms. It is composed essentially of hydrated amorphous or opalline silica with varying amounts of contaminant materials such as silica sand, clays, salts and organic matter.

 LOCALITIES:
     Diatomite deposits are in Pantabangan and Caranglan, Nueva Ecija; Basud, Camarines Norte; Kapatagan, Lanao del Norte; and in Quezon, Bukidnon.

FELDSPAR
      Feldspar is the general term for the group of rock-forming minerals that are essentially anhydrous aluminum silicates.  It is an important material in the production of glass, fired clay products, and enamel paints.  


Related to intrusions










MAGNESITE

Magnesite, a natural form of magnesium carbonate with ideal magnesia content of 47.60 percent, is an important source of magnesium for industrial purposes.  Magnesium is an essential element in plant and animal metabolism, and is added to animal feeds in the form of caustic-calcined magnesia.

 LOCALITIES:
      Lupon, Mati, Puntalinao, and Banay-banay, Davao Oriental; small deposits are in Sibuyan Island, Romblon. .

PERLITE
      Perlite is a hydrated silicic volcanic glass, which generally has a characteristic “onion-skin” or perlitic texture and a pearly luster.  When expanded or bloated by shock calcination, perlite forms an inert mass with an open texture having low bulk density, low thermal conductivity, high sound absorption and fire-resistance.


LOCALITIES:
Perlite deposits are found in Calayan Island, Cagayan; Baao, Camarines Sur; and in Maslog, Taysan, and Puro, Legazpi City




SILICA

Silica or silicon dioxide (SiO2) commonly occurs as mineral quartz in varied forms; as veins and lenses of bull quartz, as sand, pebbles, cobbles and boulders, and as siliceous clays

About 85% of silica sand are utilized in glass manufacture

 CLASSIFICATION:
1.Silica in rock form ( Mindoro)
2.Silica in fragmental form ( Tagkawayan Quezon)
3. Siliceous clays ( Siruma Peninsula, Camarines Sur)

TALC
      Talc is a layer-lattice mineral with the following composition, Mg3Si4O10- (OH)2.  It is the softest common mineral with hardness of one (1) on Moh’s scale of hardness.  Its cleavage flakes are flexible but not elastic.  It occurs in low to medium metamorphosed basic or ultrabasic rocks and in place, constitutes the greater part of the rock, producing the material known as steatite or soapstone.


LOCALITIES:
Abra, de Ilog, Mindoro Occidental; Marangas, Brooke’s Point, Palawan and in Cabangan, Zambales.



ALUMINUM

The main source of aluminum is bauxite, a mixture of gibbsite (Al(OH)3), diaspore (AlO(OH)), and boehmite (AlO(OH)).  Bauxite varies in colors from reddish-brown, white, tan, to tan-yellow.  It has dull to earthy luster and can look like clay or soil.  Bauxite forms when silica in aluminum-bearing rocks (with high feldspar content) is washed away (leached). 
The major producer of aluminum ore is Australia, which is said to produce over 40% of the world’s reserves.  Brazil, Papua New Guinea, and Jamaica are also important producers.   About 85% of all the bauxite mined worldwide is used to produce alumina for refining into aluminum metal.  Another 10% of the alumina produced is used in the manufacture of chemical, abrasive, and refractory products. The remaining 5% is used to make abrasives, refractory materials, and aluminum compounds.

Bauxite in the Philippines is commonly associated with karsted limestone and lateritic terranes.

 LOCALITIES:
These include Batag Island, Hinabangan, Corcord, Guiuan, and Western Samar, Nonoc Island, Bucas Grande

MOLYBDENUM       

Molybdenum occurs chiefly as a secondary or accessory metal in porphyry copper and copper skarn deposits in the Philippines, although it has also been documented to occur elsewhere in quartz veins, pegmatites and bedded sedimentary deposits. 
Philippine porphyry copper deposits and prospects range from gold-rich, molybdenumpoor deposits to relatively molybdenum-rich, gold-poor end members. These molybdenum-rich deposits are found in the provinces of Larap, Polillo Island, and Southern Negros while the molybdenum-deficient deposits are in Baguio and Cebu.  The molybdenum-rich, gold-deficient deposit in southwestern Negros (Binulig, Sipalay, Aya-Aya) contains 0.01% Mo with 1 ppm Au. The central Cebu porphyry copper mineralization is characterized by relatively high contents of both molybdenum and gold.






MERCURY
The term “native mercury” is used for natural mercury found associated with the mineral cinnabar.
Locality : Central Palawan



“Zambales Jade” Deposits, Zambales
       It contains sharply crystallized dodecahedral crystals of garnet, uvarovite, xenoblastic feldspar, minor diopside and sphene that lie in a granoblastic mosaic of quartz and plagioclase. This hornfelsic rock is composed of 67% feldspar (potash and plagioclase), 18% quartz, 10% garnet; 4% sphene, and 3% diopside.

“Mindoro Jade” Deposit, Occidental Mindoro
      It is composed of 40% muscovite, 50% sericite, 5% apatite and traces of quartz, calcite and chlorite. The gemstone is petrologically  termed green mica schist due to the presence of abundant sericite.

Dasol Jasper Deposit, Pangasinan
    The deposit is in San Vicente, Mabini and Barlo, Dasol.  Early prospectors used this jasper deposit as a guide in determining the relative stratigraphic location of massive sulfide bodies. The inhabitants use the jasper as sharpening stone or as aggregate for building materials.  Later, this jasper was found to be of good gem quality, thus paving the way for exploitation

Moss Opal Deposit, Ilocos Norte
   The moss opal deposit occurs as veins and lenses within fractures, cavities and flow layers of andesite.
The moss opal is milky white to brown, containing iron oxide in a moss or fernlike pattern.